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Sentry Fiproguard Spray for Dogs & Cats-07/09/2016
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Flea and Tick Killer for Dogs and Cats.Structure such as solid, liquid, aerosol etc.
Form: aerosolDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 2024P.O. Box 540399
Omaha NE 68154
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 132259-10-0 -- -- -- -- -- 000067-63-0 -- F, Xi -- -- -- -- 000111-90-0 -- 5.0-10.0 -- -- -- -- 025013-16-5 -- <0.5 -- -- -- -- 120068-37-3 -- 0.29 N, T -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)Compressed air
132259-10-0
---- No -- -- -- No No Isopropanol
000067-63-0
200-661-7-- No H225, H319, H336 P102, P210, P233, P241, P242, P243, P261, P264, P271, P280, P405, P501, P303+P361+P353, P370+P378, P337+P313, P305+P351+P338, P304+P340, P312, P403+P233, P403+P235 No No Diethylene glycol ethyl ether
000111-90-0
203-919-75.0-10.0 No -- -- -- No No Butylated hydroxyanisole (BHA)
025013-16-5
246-563-8<0.5 Yes H411, H315, H319, H351, H361 -- No No Fipronil
120068-37-3
424-610-50.29 No H331, H311, H301, H372, H400, H410 -- No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H225 : Highly flammable liquid and vapourH301 : Toxic if swallowedH311 : Toxic in contact with skinH315 : Causes skin irritationH319 : Causes serious eye irritationH331 : Toxic if inhaledH336 : May cause drowsiness or dizziness.H351 : Suspected of causing cancerH361 : Suspected of damaging fertility or the unborn childH372 : Causes damage to organsH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effectsH411 : Toxic to aquatic life with long lasting effects
- P102 : Keep out of reach of childrenP210 : Keep away from heat/sparks/open flames/hot surfacesP233 : Keep container tightly closedP241 : Use explosion-proof electrical/ventilating/light/…/equipmentP242 : Use only non-sparking toolsP243 : Take precautionary measures against static dischargeP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP271 : Use only outdoors or in a well-ventilated areaP280 : Wear protective gloves/protective clothing/eye protection/face protectionP312 : Call a POISON CENTER or doctor/physician if you feel unwellP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP337+P313 : Get medical advice/attentionP370+P378 : In case of fire: Use … for extinctionP405 : Store locked upP501 : Dispose of contents/container to
- GHS02 : FlammableGHS06 : ToxicGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :July 09, 2016 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING2* 3 0 -
V.O.C Information
Volatile Organic Compounds %/Wt. With Solvent : 95.0
Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels6.3 -
SVHC declaration
This product does not contain any Substances of Very High Concern (SVHC).
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Warnings
Hazard Statements
Danger. Extremely Flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of causing cancer. May cause drowsiness or dizziness.
Precautionary statements
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames and hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing vapors or mists. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Wear eye protection.
Response
IF in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
IF inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell.
IF exposed or concerned: Get medical advice.
In case of fire: Use water spray, carbon dioxide or alcohol- resistant foam to extinguish.
Storage
Protect from sunlight. Do not expose to temperatures exceeding 50 deg. C/122 deg. F. Store in a well-ventilated place. Store locked up.
Disposal
Dispose in accordance with local and national regulations. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Danger. Extremely Flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of causing cancer. May cause drowsiness or dizziness.
Potential Health Effects
Eye Contact: Contact may cause irritation with redness, pain and tearing.
Skin Contact: May cause irritation and effects similar to ingestion. Fipronil is absorbed through the skin.
Inhalation: Inhalation of vapors may cause irritation of the mucous membranes and upper respiratory tract and central nervous system effects such as dizziness, drowsiness and headache and effects similar to ingestion.
Ingestion: Swallowing may cause may cause drowsiness, dizziness, sweating, nausea, vomiting, headache, abdominal pain, dizziness, agitation, weakness, and tonic-clonic seizures. -
Chronic health effects
From SDS:
Prolonged or repeated exposure may cause neurotoxicity and effects on the thyroid and liver. -
Carcinogenicity
Butylated hydroxyanisole is classified by IARC as a group 2B carcinogen and by NTP as reasonably anticipated to be a carcinogen. None of the other components are listed as carcinogens or suspected carcinogens by IARC, NTP, ACGIH or OSHA. Fipronil cause only species-specific tumours in studies with rats and mice. -
Handling information
Avoid contact with eyes, skin and clothing. Wash thoroughly with soap and water after handling. Do not eat, drink or smoke when handling this material. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove contaminated clothing and launder before re-use. Keep product away from heat, sparks and flames. Do not smoke while using. Do not leave the can in direct sunlight. Do not puncture or incinerate container, even when empty. Store as indicated on product packaging. Do not expose to temperatures above 120 deg. F / 50 deg. C. Protect containers from physical damage. Store in a cool area. Keep away from excessive heat and open flames. Store out of direct sunlight. Store away from oxidizers. PESTICIDE STORAGE: Store in original container. Keep away from fire, sparks and heated surfaces. Store in a cool, dry place inaccessible to children and pets. -
Disposal information
Dispose in accordance with all local, state and federal regulations. PESTICIDE DISPOSAL AND CONTAINER HANDLING: Do not puncture or incinerate. Non-refillable container. If empty: Place in trash or offer for recycling if available. If partly filled: Call your local solid waste agency for disposal instructions. -
First Aid
Eye Contact: Immediately flush eyes with water for 15 minutes while lifting the upper and lower lids. Get medical attention if irritation persists.Skin Contact: Wash hands with soap and water after handling. If irritation develops and persists or symptoms of exposure develop, get medical attention.Inhalation: Remove person to fresh air. If irritation occurs or symptoms develop, get medical attention.Ingestion: Rinse mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to a person who is unconscious or convulsing. Get medical attention.
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